Local structure and coordination define adsorption in a model Ir₁/Fe₃O₄ single-atom catalyst

Z. Jakub, J. Hulva, M. Meier, R. Bliem, F. Kraushofer, M. Setvin, M. Schmid, U. Diebold, C. Franchini, G. S. Parkinson

Angew. Chem. Int. Ed. 58 (2019) 13961-13968

Single-atom catalysts (SACs) bridge homo- and heterogeneous catalysis because the active site is a metal atom coordinated to surface ligands. The local binding environment of the atom should thus strongly influence how reactants adsorb. Now, atomically resolved scanning-probe microscopy, X-ray photoelectron spectroscopy, temperature-programmed desorption, and DFT are used to study how CO binds at different Ir₁ sites on a precisely defined Fe₃O₄(001) support. The two- and five-fold-coordinated Ir adatoms bind CO more strongly than metallic Ir, and adopt structures consistent with square-planar Ir^I and octahedral Ir^III complexes, respectively. Ir incorporates into the subsurface already at 450 K, becoming inactive for adsorption. Above 900 K, the Ir adatoms agglomerate to form nanoparticles encapsulated by iron oxide. These results demonstrate the link between SAC systems and coordination complexes, and that incorporation into the support is an important deactivation mechanism.

Corresponding author: Gareth S. Parkinson (parkinson).

You can download a PDF file of this open-access article from Angewandte Chemie International Edition or from the IAP/TU Wien web server.