How to cleave cubic perovskite oxides

I. Sokolović, M. Schmid, U. Diebold, M. Setvín

Institut für Angewandte Physik, TU Wien, 1040 Wien, Austria

Rev. Sci. Instrum. 96 (2025) 035113

Surfaces of cubic perovskite oxides attract significant attention for their physical tunability and high potential for technical applications. Bulk-terminated surfaces are desirable for theoretical modeling and experimental reproducibility, yet there is a lack of methods for preparing such well-defined surfaces. We discuss a method for strain-assisted cleaving of perovskite single crystals, using a setup easily transferable between different experimental systems. The details of the cleaving device and the procedure were optimized in a systematic study on the model cubic perovskite oxide SrTiO3. The large-area morphology and typical distribution of surface terminations on cleaved SrTiO3(001) are presented, with specific guidelines on how to distinguish well-cleaved surfaces from conchoidally fractured ones. The cleaving is applicable to other cubic perovskites, as demonstrated on KTaO3(001) and BaTiO3(001). This approach opens up a pathway for obtaining high-quality surfaces of this promising class of materials.

Corresponding author: Igor Sokolović (sokolovic at iap_tuwien_ac_at).

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